Title

Generation and Reactivity of a One-electron Oxidized Manganese(V) Imido Complex bearing a Macrocyclic Tetraamido Ligand

Document Type

Journal Article

Publication Date

2019

Keywords

coordination chemistry, hydrogen atom transfer, imido transfer, one-electron oxidation, manganese

DOI

10.1002/chem.201902405

Abstract

The synthesis and X‐ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N‐Mes)]− (1), are reported. Compound 1 is oxidized by [(p‐BrC6H4)3N]+.[SbCl6]− and the resulting MnVI species readily undergoes H‐atom transfer and nitrene transfer reactions.

Source Publication

Chemistry - A European Journal

Volume Number

25

Issue Number

56

ISSN

0947-6539

First Page

12895

Last Page

12899

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