Generation and Reactivity of a One-electron Oxidized Manganese(V) Imido Complex bearing a Macrocyclic Tetraamido Ligand

Authors

Huatian Shi, City University of Hong Kong
Jianhui Xie Xie, Hefei University of Technology
William W. Y. Lam, Technological and Higher Education Institute of Hong Kong (THEi)Follow
Wai‐Lun Man, Hong Kong Baptist University
Chi‐Keung Mak, City University of Hong Kong
Shek‐Man Yiu, City University of Hong Kong
Hung Kay Lee, City University of Hong Kong
Tai‐Chu Lau, City University of Hong Kong

Staff Page Link

Dr LAM Wai Yan, William

Document Type

Journal Article

Publication Date

2019

Keywords

coordination chemistry, hydrogen atom transfer, imido transfer, one-electron oxidation, manganese

DOI

10.1002/chem.201902405

Abstract

The synthesis and X‐ray structure of a new manganese(V) mesitylimido complex with a tetraamido macrocyclic ligand (TAML), [MnV(TAML)(N‐Mes)]− (1), are reported. Compound 1 is oxidized by [(p‐BrC6H4)3N]+.[SbCl6]− and the resulting MnVI species readily undergoes H‐atom transfer and nitrene transfer reactions.

Source Publication

Chemistry - A European Journal

Volume Number

25

Issue Number

56

ISSN

0947-6539

First Page

12895

Last Page

12899

Recommended Citation

Shi, H.,Xie, J.,Lam, W. W.,Man, W.,Mak, C.,Yiu, S.,Lee, H.,& Lau, T. (2019). Generation and Reactivity of a One-electron Oxidized Manganese(V) Imido Complex bearing a Macrocyclic Tetraamido Ligand. Chemistry - A European Journal, 25 (56), 12895-12899. http://dx.doi.org/10.1002/chem.201902405