Title

Aggregation and DNA intercalation properties of Di(isocyano) rhodium(I) Diimine complexes

Document Type

Journal Article

Publication Date

2011

DOI

10.1021/om200723j

Abstract

A series of di(isocyano) rhodium(I) diimine complexes has been synthesized and characterized. Owing to the aggregation affinity of these complexes, they were found to exhibit thermochromism. To provide further insights into the aggregation affinity of these complexes, the enthalpy (δH) and entropy (δS) changes of dimerizations of some of the complexes have been determined. In addition, the DNA intercalation properties of these complexes have also been investigated by the DNA unwinding assay.

Source Publication

Organometallics

Volume Number

30

Issue Number

21

First Page

5873

Last Page

5881

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